Dichlorido-1κCl,3κCl-hexakis[1,1,2,2,3,3(η5)-cyclopentadienyl]di-μ2-oxido-1:2κ2 O:O;2:3κ2 O:O-trizirconium(IV)
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چکیده
The title compound, [Zr₃(C₅H₅)₆Cl₂O₂], exists as discrete mol-ecules possessing a series of three Cp(2)Zr units (Cp is cyclo-penta-dien-yl) bridged by oxide ligands and end-capped by chloride ligands. The Cp planes in the central and terminal zirconocene units form dihedral angles of 53.3 (2) and 53.5 (2)°, respectively. The two Zr-O-Zr bridge angles are nearly linear and form a planar Zr₃O₂ core. The mol-ecule bears C2 symmetry with the central Zr atom lying on a crystallographic twofold axis.
منابع مشابه
Dichlorido-1κCl,3κCl-hexakis[1,1,2,2,3,3(η5)-methylcyclopentadienyl]di-μ2-oxido-1:2κ2 O:O;2:3κ2 O:O-trihafnium(IV)
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